
Home  Instruments  Science  Experiments  SiteMap 
How thick should my sample be?
Cautionary remarks
The most common answer to the question "How thick should my sample be?", or more generally "What should be the dimensions of my sample?", is that the sample should be a "10% scatterer", which presumably means that 10% of the neutrons that enter the sample are scattered at least once (or does it means that 10% of the neutrons are scattered once and then leave without being absorbed or scattered again?) The argument is that a "10%" scatterer scatters roughly 10% of the scattered neutrons a second time (and ~10% of those neutrons yet again), and that this amount of multiple scattering is in some sense acceptable.The fact that a sample is a "10% scatterer" does not necessarily imply that ~10% of the scattered neutrons are scattered again before they exit the sample. For example, Wuttke (Physica B 292, 194 (2000)) has shown that a thin annular sample whose transmission is 96% for a tightly collimated beam, and ~94% for a beam that fully illuminates the sample, scatters ~10% of the scattered neutrons a second time. This implies that a "10% scatterer", meaning a sample with little absorption and a transmission of about 90% (depending how it is measured), scatters something like 1525% of the neutrons a second time.
An experimentalist sometimes has to decide the dimensions of his or her sample using a calculated value for the transmission. This implies that the macroscopic scattering and absorption cross sections are known. The number density can generally be calculated quite well, and the microscopic cross sections are generally obtained from a compilation such as that of Sears in Neutron News 3 (3), 26 (1992). This approach can be quite misleading, especially for hydrogenous materials. This is discussed below, under the heading Scattering cross sections .
Calculating the scattering probability given the dimensions of a sample
Given the proposed geometry (we shall consider slabs, cylinders and annular samples), and the relevant macroscopic scattering and absorption cross sections , and respectively, the scattering probability , S, can be calculated. Note that S is the probability of scattering at least once (followed by escape, absorption or additional scattering); in general it is an overestimate of the total scattering probability.For a slab sample of thickness, t, whose normal is at an angle to the beam,
For a cylindrical sample of radius R, with axis normal to the beam,
where
For an annular sample with inner and outer radii and respectively (annular thickness ), whose axis is normal to the beam,
where and if , otherwise .
Calculating the dimensions of a sample given its scattering probability
Slab sample
For a slab sample normal to the beam, the value t can be obtained directly from the the single scattering probability expression:
There is no solution if .
Annular Sample
For the general case there is no analytical solution so the integral must be calculated numerically. An approximate solution (which is only valid if ) is based on the approximate result
which yields
Again there is no solution if .
Cylindrical Sample
In this case there is again no analytical solution. The integral can be calculated numerically as a function of the dimensionless magnitude, R.
Scattering cross sections
The macroscopic total scattering cross section is not the same as the macroscopic bound atom scattering cross section ; depends on much more, including the temperature, the incident neutron energy, and the physics and chemistry, indeed the structure and dynamics of the sample. (Consider the ideal gas, a rigid crystalline solid, graphite, beryllium, water, the ammonium halides, etc.)The macroscopic bound atom scattering cross section may be calculated as follows:
with , and . In these expressions, is the number density of atoms of element k, is the total (coherent plus incoherent) bound atom scattering cross section of element k, is the number density of scattering units, is the number of atoms of element k per scattering unit, is the mass density, is Avogadro's number, M is the mass ("molecular weight") of a scattering unit, and is the atomic mass of element k.
The macroscopic total scattering cross section , which appears in the expression for S (see the calculations of the scattering probabilities for the different geometries: slab sample, cylindrical sample and annular sample ), may be written as
where is the macroscopic differential cross section for scattering into solid angle and scattered energy .
The need to distinguish between and is particularly important when working with hydrogenous materials. For example for water is roughly 170 b/molecule whereas at 9 (1 meV) is ~240 b/molecule. On the other hand at 1.8 (25 meV) is about 100 b/molecule.
The macroscopic total cross section is defined as the sum of the macroscopic total scattering cross section and the macroscopic absorption cross section :
.
Report errors or make inquiries to Inma Peral, <inma@nist.gov>
Last modified 02August2007 by website owner: NCNR (attn: John Copley)