The theory and analysis of SANS from
BICONTINOUS
MORPHOLOGIES
is a major research interest in the NIST Center for
Neutron Research
The
LEVELED
WAVE
MODEL
has been developed to describe the geometry of such structures and
calculate the scattering from them.
- Scattering Properties of the Leveled-Wave
Model of Random Morphologies
N. F. Berk, Phys. Rev.
A44, 5069 (1991).
The LWM is
described and extended. It is shown how fractal roughness can be
incorporated into the model.
- Scattering
Properties of a Model Bicontinuous Structure with a Well Defined Length
Scale
N. F. Berk, Phys. Rev. Lett.,5821, 2718
(1987).
The leveled wave model is introduced. Its relationship to Cahn's
original construction is discussed. It is shown that the model can
produce a single Bragg peak at the characteristic wavenumber
of the structure. The theoretical behavior of the
characteristic peak with scattering contrast variation is shown.
The characteristic peak vanishes when the only
contrast is between the surfactant film and the bulk, with equal volume
fractions on either side of the film, as observed in scattering
from micromulsions.
-
Structure of a Triglyceride Micremulsion: A Small Angle Neutron
Scattering Study
S. F. Trevino, R. Joubran, N. Parris, and N. F. Berk,
Langmuir, 10,
2547 (1994).
The LWM is applied to SANS from a novel microemulsion.
More recent work in progess
has revealed limitations of the current form of the LWM in
this system, in which the two sides of the surfactant phase have very
different morphologies.
-
Analysis of SANS from Controlled Pore Glasses
N. F. Berk, C. J. Glinka, W. HAller, and L. C. Sander,
Meter. Res. Soc. Symp. Proc.166, 409 (1990).
The LWM is applied to controlled pore glasses, and the pore size
distribution is discussed.
|