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Applications of Combinatorial Materials Science in Silicon Microelectronics

Martin Green, Ceramics Division

The Si microelectronics community is currently faced with major materials challenges to further scaling. The SiO2/polycrystalline Si gate stack that has served the industry for 35 years must now be entirely replaced with one having a higher capacitance and lower power dissipation. At a minimum, the interfaces of the new gate stack, (HfO2/metal, for example), must be thermally stable with respect to interfacial reactions, and the changes in electrical properties that would ensue. In this talk, I will describe research aimed at understanding the thermal as well as electrical stability of metal gate electrode layers on HfO2, a likely high-k gate dielectric. Combinatorial methodologies, ideally suited for this problem since a wide variety of metal electrode layers will be examined, will be utilized to determine the ideal composition and structure of the metal gate electrode.

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